Out of curiosity, I looked it up and here are all the people to get a perfect score:

2003:

Excal- Link Vs. Fox McCloud
Kirin17- Link Vs. Fox McCloud
FastFalcon07- Samus Vs. KOS-MOS
KrusTy the KloWn- Mario Vs. Crono
Xuxon- Mario Vs. Crono
Starion- Mega Man Vs. Snake

Sp2004:

Garsha- The Legend of Zelda: Wind Waker Vs. Skies of Arcadia

2004:

Xuxon- Mega Man Vs. Earthworm Jim
ps2rulezzz- Ryu Hyubasa Vs. Jill Valentine

Sp2005:

None

2005:

Team Rocket Elite- Zero Vs. Ryu Hyubasa
outback- Samus Aran Vs. Yuri Hyuga
and now I dance- Ganondorf Vs. Auron
Master Moltar- Crono Vs. Tommy Vercetti

2006:

Pats_Dynasty- Super Mario Bros. Vs. Madden NFL*
Inviso: Grand Theft Auto Vs. Warcraft*

Fall 2006:

ActJef1077- Rikku Vs. Lenneth Valkyrie**
Camden- Rikku Vs. Lenneth Valkyrie**
Big Bob- Rikku Vs. Lenneth Valkyrie**
Weird Kirby Dude- Rikku Vs. Lenneth Valkyrie**
Figlar2000- Rikku Vs. Lenneth Valkyrie**
Team Rocket Elite- Rikku Vs. Lenneth Valkyrie**
Layzerbeam- Rikku Vs. Lenneth Valkyrie**
XII is cool- Jill Valentine Vs. Sheena Fujibayashi
Vlado- Terra Bradford Vs. Sarah Kerrigan
RX7InfinitiIII- KOS-MOS Vs. Amy Rose
XII is cool- Ganondorf Vs. Vincent Valentine
stingers135- Kirby Vs. The Prince of Persia
DarkLink89- Solid Snake Vs. Squall Leonhart
redsox 777- Samus Aran Vs. Rikku
Luster Soldier- Tifa Lockheart Vs. Princess Peach
Lopen- Aeris Gainsborough Vs. Princess Zelda
Vlado- Solid Snake Vs. Yoshi


Xuxon, Team Rocket Elite, XII is cool, and Vlado are the only ones to get a perfect score more than once.

*First string of two perfects in a row.
**Most perfects in one match (7)

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